By H.A. Kiehne
This sensible reference continues to be the main finished consultant to the basic theories, innovations, and methods used for battery operation and layout. It comprises new and revised chapters concentrating on the protection, functionality, caliber, and enhancement of assorted batteries and battery platforms. From car, electrochemical, and high-energy purposes to procedure implementation, choice, and standardization, the second one variation offers professional discussions on electrochemical power garage, some great benefits of battery-powered traction, the disposal and recycling of used batteries, danger prevention, and the chemistry and physics of lithium fundamental batteries.
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Extra info for Battery Technology Handbook, Second Edition (Electrical and Computer Engineering)
E Only approximated data that depend on the oxidation state of the nickel hydroxide. f Hydrogen is absorbed by special alloys. g Depends on the alloy, used for hydrogen storage. h Operating temperature 300 to 400 8C. i Value depends on the size of the separate tanks for the active material. a Special battery systems 11 Sodium/sulfur h 12 Sodium/nickel chloride h 13 Zinc/bromine 10 NiOOH Nickel/cadmium 8 NiOOH PbO2 Secondary batteries 7 Lead-acid with ai: activity of the reacting component i (approximately the concentration) ðmole ?
During the initial two sections of the charging period, slight cooling is observed on account of the reversible heat effect that consumes heat at a constant rate proportional to the current. 3 and Fig. 10). Thus, during the ﬁnal sections of the charging period, a growing amount of heat is generated. 25 Wh. The main reason is that the reversible heat effect generates additional heat during discharge, while it compensates for heat generation during charging. The situation is different for sealed nickel/cadmium batteries, due to the internal oxygen cycle.
But the amount of stored energy per weight or volume is comparatively small. In batteries such a double layer also exists, and the large surface area of the active material gives rise to a high double layer capacitance when impedance measurements are made. The real battery capacity, however, is much higher and based on chemical reactions. As a consequence, each charge/discharge cycle changes the physical structure of the electrodes, and these changes inevitably cause an aging process. For this reason, with batteries the number of possible charge/discharge cycles is limited, and performance changes over service life are unavoidable.